Adsorption characteristics of NH2-UiO-66 for the removal of hematite inorganic dye from industrial wastewater: Isotherm, thermodynamic, and kinetic study

Document Type : Research Paper

Authors

Department of Chemical Engineering, University of Qom, Qom, Iran

Abstract

Metal-organic frameworks (MOFs) have emerged as a class of highly promising materials for wastewater dye removal due to their unique properties. However, the existing body of research has primarily concentrated on the removal of organic dyes. To address this gap and contribute to advancements in water treatment technologies, this study investigates the efficacy of a zirconium- terephthalate-based MOF for the adsorptive removal of hematite, an inorganic dye, from aqueous environments. This investigation explored the influence of key parameters, including initial dye concentration, pH, adsorbent dosage, and adsorption temperature, on the adsorption capacity of NH2-UiO-66 for hematite. The findings revealed that elevated temperatures and initial dye concentrations promoted hematite adsorption onto NH2-UiO-66. Furthermore, the analysis of experimental data demonstrated concordance with the theoretical predictions of both the linearized Freundlich and Langmuir isotherm models. The study of kinetic models reveals that the pseudo-first-order model can adequately describe experimentally obtained data. The adsorption thermodynamic parameter ΔG0 was found to be approximately -3.70, -3.94, and -4.19 kJ.mol−1 at 298, 313, and 328 K, respectively. Furthermore, the ΔH0 and ΔS0 parameters were 5.15 kJ.mol-1 and 54.3 J.mol-1, respectively, indicating an endothermic adsorption mechanism. Further investigation found that the regeneration effectiveness is greater than 92% even after three adsorption cycles.

Keywords

Main Subjects

References

  1. Fang Y, Zhang L, Zhao Q, Wang X, Jia X, (2019). Application of acid-promoted UiO-66-NH2 MOFs in the treatment of wastewater containing methylene blue. Chemical Papers, pp: 73:1401-1411.
  2. Zeng L, Xiao L, Long Y, Shi X, (2018). Trichloroacetic acid-modulated synthesis of polyoxometalate@UiO-66 for selective adsorption of cationic dyes. J. Colloid Interface Sci., pp: 516:274–283.
  3. He Q, Chen Q, Lü M, Liu X, (2014). Adsorption behavior of rhodamine B on UiO-66. Chin. J. Chem. Eng., pp: 22:1285–1290.
  4. Roopaei H, Zohdi AR, Abbasi Z, Bazrafkan M, (2014). Preparation of new photocatalyst for removal of alizarin red-s from aqueous solution. Indian Journal of Science and Technology, pp: 7:1882–1887.
  5. Gneedy AH, Dryaz AR, Said MSh, AlMohamadi HA, Ahmed SA, Elsayed R, Soliman NK, (2022). Application of marine algae separate and in combination with natural zeolite in dye adsorption from wastewater: a review, Egyptian Journal of Chemistry, pp: 65:589-616.
  6. Sağlam S, Türk FN, Arslanoğlu H, (2023). Use and applications of metal-organic frameworks (MOF) in dye adsorption: review. Journal of Environmental Chemical Engineering, pp: 11: 110568.
  7. Lan D, Zhu H, Zhang J, Li Sh, Chen Q, Wang Ch, Wu T, Xu M, (2022). Adsorptive removal of organic dyes via porous materials for wastewater treatment in recent decades: a review on species, mechanisms and perspectives. Chemosphere, pp: 293:133464.
  8. De Sousa SR, Rengel HD, Voigt FD, Machado RAF, De Fátima MR, Marangoni C, (2023) Treatment of real textile wastewater by coagulation/flocculation integrated with direct contact membrane distillation. Separation Science and Technology, pp: 58:2394-2410.
  9. Wang H, Song J, Yan M, Li J, Yang J, Huang M, Zhang R, (2023). Waste lignin-based cationic flocculants treating dyeing wastewater: fabrication, performance, and mechanism. Science of The Total Environment, pp: 874:162383.
  10. Kolya H, Kang CW, (2023). Bio-based polymeric flocculants and adsorbents for wastewater treatment. Sustainability, pp: 15:1-36.
  11. Asath Murphy MS, Jovitha Jane D, Sahaya LS, Robin RS, Palanichamy J, Kalivel P, (2023). Electrochemical treatment of textile wastewater using copper electrodes. J Environ Sci Health A Tox Hazard Subst Environ Eng, pp: 58:971-980.
  12. Chen Zh, Feng M, Wang Y, Ma Q, Yin Q, (2023) Construction of a novel magnetic levitation iron–carbon micro-electrolysis treatment system for dye wastewater and its anti-passivation strategy. Environ. Sci.: Water Res. Technol., pp: 9:2076-2088.
  13. Xie J, Zou X, Chang Y, Xie J, Liu H, Cui MH, Zhang TC, Chen C, (2023). The microbial synergy and response mechanisms of hydrolysis-acidification combined microbial electrolysis cell system with stainless-steel cathode for textile-dyeing wastewater treatment. Sci Total Environ., pp:10:158912.
  14. Mim S, Hashem MA, Payel S, (2023). Coagulation-adsorption-oxidation for removing dyes from tannery wastewater. Environ Monit Assess., pp:195: article number 695.
  15. Sudirgo MM, Surya RA, Kristianto H, Prasetyo S, Sugih AK, (2023). Application of xanthan gum as coagulant-aid for decolorization of synthetic congo red wastewater. Heliyon, pp: 9: e15011.
  16. Yu H, Liu Y, Cong Sh, Xia Sh, Zou D, (2023). Review of Mo-based materials in heterogeneous catalytic oxidation for wastewater purification. Separation and Purification Technology, pp: 312:123345.
  17. Shokoohi R, Godini K, Latifi Z, (2023). Catalytic Oxidation of reactive blue 222 dye using peroxymonosulfate activated by Mn3O4: parameter optimization using response surface methodology. Inorganic Chemistry Communications, pp: 149:1104.
  18. Eskikaya O, Isik Z, Arslantas C, Yabalak E, Balakrishnan D, Dizge N, Rao KS, (2023). Preparation of hydrochar bio-based catalyst for fenton process in dye-containing wastewater treatment. Environmental Research, pp: 216:114357.
  19. Yu H, Cai D, Li Sh, Gao C, Xue L, (2023). Tight UF membranes with ultrahigh water flux prepared by in-situ growing ZIF particles in NIPS process for greatly enhanced dye removal efficiency. Journal of Membrane Science, pp: 666:121136.
  20. Zhu K, Mohammed S, Tang H, Xie Z, Fang S, Liu S, (2023). ZIF-67/SA@PVDF ultrafiltration membrane with simultaneous adsorption and catalytic oxidation for dyes. Sustainability, pp: 15:2879.
  21. Thoa LThK, Thao TThPh, Nguyen-Thi M, Duc Chung N, Ooi ChW, Park SM, Lan TTh, Quang HT, Khoo KSh, Show PL, Duc Huy N, (2023) Microbial biodegradation of recalcitrant synthetic dyes from textile-enriched wastewater by fusarium oxysporum, Chemosphere, pp: 325:138392.
  22. Selvan BK, Pandiyan R, Vaishnavi M, Das S, Thirunavoukkarasu M, (2023). Ameliorative biodegradation of hazardous textile industrial wastewater dyes by potential microalgal sp. Biomass Conv. Bioref., pp:13:13481–13492.
  23. Embaby MS, Elwany SD, Setyaningsih W, Saber MR, (2018). The adsorptive properties of UiO-66 towards organic dyes: a record adsorption capacity for the anionic dye alizarin red s. Chin. J. Chem. Eng., pp: 26:731-739.
  24. Chen Q, He Q, Lv M, Xu Y, Yang H, Liu X, Wei F, (2015). Selective adsorption of cationic dyes by UiO-66-NH2. Applied Surface Science, pp: 327:77-85.
  25. Couillard D, (1994). The use of peat in wastewater treatment. Water Research, pp: 28:1261-1274.
  26. Bu X.H., Zaworotko M.J., Zhang Zh., Metal-Organic Framework from Design to Applications, first ed., Springer, Nature Switzerland, 2020.
  27. Lin H, Jie B, Ye J, Zhai Y, Luo Zh, Shao G, Chen R, Zhang X, Yang Y, (2023). Recent advance of macroscopic metal-organic frameworks for water treatment: a review. Surfaces and Interfaces, pp: 36:102564.
  28. Kaur H, Devi N, Siwal SS, Alsanie WF, Thakur MK, (2023). Metal–organic framework-based materials for wastewater treatment: superior adsorbent materials for the removal of hazardous pollutants. ACS Omega, pp: 8:9004–9030.
  29. Tambat SN, Ahirrao DJ, Pandit AB, Jha N, Sontakke ShM, (2020). Hydrothermally synthesized N2-UiO-66 for enhanced and selective adsorption of cationic dyes. Environmental Technology & Innovation, pp:19:101021.
  30. Li Y, Liu Y, Gao W, Zhang L, Liu W, Jingjing L, Wang Z, Deng YJ, (2014). Microwave-assisted synthesis of UiO-66 and its adsorption performance towards dyes. Cryst. Eng. Comm., pp: 16:7037–7042.
  31. Zhang KD, Tsai FC, Ma N, Xia Y, Liu HL, Zhan XQ, Yu XY, Zeng XZ, Jiang T, Shi D, Chang CJ, (2017). Adsorption behavior of high stable Zr-based MOFs for the removal of acid organic dye from water. Materials, pp:10:205.
  32. Tambat SN, Sane PK, Suresh S, Varadan ON, Pandit AB, Sontakke ShM, (2018). Hydrothermal synthesis of NH2-UiO-66 and its application for adsorptive removal of dye. Advanced Powder Technology, pp: 29:2626-2632.
  33. Mousavi AV, Ahmadipouya S, Shokrgozar A, Molavi H, Rezakazemi M, Ahmadijokani F, Arjmand M, (2021). Adsorption performance of UiO-66 towards organic dyes: effect of activation conditions. Journal of Molecular Liquids, pp: 321:114487.
  34. Qiu J, Feng Y, Zhang X, Jia M, Yao J, (2017). Acid-promoted synthesis of UiO-66 for highly selective adsorption of anionic dyes: adsorption performance and mechanisms. J. Colloid Interface Sci., pp: 499:151-158.
  35. Molavi H, Hakimian A, Shojaei A, Raeiszadeh M, (2018). Selective dye adsorption by highly water stable metal–organic framework: long term stability analysis in aqueous media. Appl. Surf. Sci., pp: 445:424-436.
  36. Mohammadi A, Sedighi M, Afsari M, (2022). Optimization of the synthesis of UiO-66-NH2 catalyst and its application for removing organophosphorus pesticides from wastewater. J. Hydraul. Struct., pp: 8:1-16.
  37. Yang J, Dai Y, Zhu X, Wang Z, Li Y, Zhuang Q, Shi J, Gu J, (2015). Metal–organic frameworks with inherent recognition sites for selective phosphate sensing through their coordination-induced fluorescence enhancement effect. J. Mater. Chem. A, pp: 3:7445-7452.
  38. Guo Zh, Xiao Ch, Maligal-Ganesh RV, Zhou L, Goh TW, Li X, Tesfagaber D, Thiel A, Huang W, (2014). Pt-nanoclusters confined within metal−organic framework cavities for chemoselective cinnamaldehyde hydrogenation. ACS Catal., pp: 4:1340−1348.
  39. Forbes, E., Franks, G. V. (2013). Selective separation of hematite from quartz by flotation using a temperature responsive polymer. Proceeding of the Iron Ore Conference, Perth, Australia.
  40. Abaka-Wood BG, Addai-Mensah J, Skinner W, (2017). A study of flotation characteristics of monazite, hematite, and quartz using anionic collectors. International Journal of Mineral Processing, pp: 158:55-62.
  41. Yang Zh, Han Y, Teng Q, Zhang G, Liu Sh, (2023) Aggregation process of fine hematite particles suspension using xanthan gum in the presence of Fe (III). Arabian Journal of Chemistry, pp: 16:104539.
  42. Fan G, Wang L, Cao Y, Li Ch, (2020). Collecting agent–mineral interactions in the reverse flotation of iron ore: a brief review. Minerals, pp: 10:681.
  43. Shrimali K, Jin J, Vaziri Hassas B, Wang X, Miller JD, (2016). The surface state of hematite and its wetting characteristics. J. Colloid Interface Sci., pp: 477:16–24.
  44. Ishikawa K, Yoshioka T, Sato T, Okuwaki A, (1997). Solubility of hematite in LiOH, NaOH and KOH solutions. Hydrometallurgy, pp: 45:129-135.
  45. Priyantha N, Lim LBL, Dahri MKh, Tennakoon DTB, (2013). Dragon fruit skin as a potential low-cost biosorbent for the removal of manganese (II) ions. Journal of Applied Sciences in Environmental Sanitation, pp: 8:179-188.
  46. Dada AO, (2012). Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk. IOSR Journal of Applied Chemistry, pp: 3:38-45.
  47. Kara M, Yuzer H, Sabah E, Celik MS, (2007). Adsorption of cobalt from aqueous solutions onto sepiolite. Water Res., pp: 37:224–232.

Files

Share

How to cite

Statistics